Daily Practice Problems
NEET Chemistry
Coordination Compounds
daily practice problem

Question 1:

An example of a sigma bonded organometallic compound is :

(a) Grignard's reagent

(b) Ferrocene

(c) Cobaltocene

(d) Ruthenocene [Level: Moderate]

 

Question 2:

Which of the following has longest C–O bond length? (Free C–O bond length in CO is 1.128Å)

(a) Ni(CO)4

(b) [Co(CO)4]

(c) [Fe(CO)4]2–

(d) [Mn(CO)6]+ [Level: Moderate]

 

Question 3:

The name of complex ion, [Fe(CN)6]3– is :

(a) Hexacyanoiron (III) ion

(b) Hexacyanitoferrate (III) ion

(c) Tricyanoferrate (III) ion

(d) Hexacyanidoferrate (III) ion [Level: Moderate]

 

Question 4:

Among the following complexes the one which shows zero crystal field stabilization energy (CFSE):

(a) [Mn(H2O)6]3+

(b) [Fe(H2O)6]3+

(c) [Co(H2O)6]2+

(d) [Co(H2O)6]3+ [Level: Moderate]

 

Question 5:

The anion of acetylacetone (acac) forms Co(acac)3 chelate with Co3+. The rings of the chelate are

(a) three membered

(b) five membered

(c) four membered

(d) six membered [Level: Difficult]

 

Question 6:

The correct IUPAC name for [CrF2(en)2]Cl is:

(a) Chlorodifluoridobis (ethylene diamine) chromium (III)

(b) Chlorodifluoridoethylenediaminech-romium (III) chloride

(c) Difluoridobis (ethylene diamine) chromium (III) chloride

(d) Difluorobis-(ethylene diamine) chromium (III) chloride [Level: Moderate]

 

Question 7:

What kind of isomerism exists between [Cr(H2O)6]Cl3 (violet) and [Cr(H2O)5Cl] Cl2.H2O (greyish-green)?

(a) Linkage isomerism

(b) Solvate isomerism

(c) Ionisation isomerism

(d) Coordination isomerism [Level: Easy]

 

Question 8:

The compounds [Co(SO4)(NH3)5]Br and [Co(SO4)(NH3)5]Cl represent

(a) linkage isomerism

(b) ionisation isomerism

(c) coordination isomerism

(d) no isomerism [Level: Moderate]

 

Question 9:

The stabilisation of coordination compounds due to chelation is called the chelate effect. Which of the following is the most stable complex species?

(a) [Fe(CO)5]

(b) [Fe(CN)6]3–

(c) [Fe(C2O4)3]3–

(d) [Fe(H2O)6]3+ [Level: Difficult]

 

Question 10:

Which of the following complexes formed by Cu2+ ions is most stable?

(a) Cu2+ + 4NH3 à [Cu(NH3)4]2+, log K = 11.6

(b) Cu2+ + 4CN à [Cu(CN)4]2–, log K = 27.3

(c) Cu2+ + 2en à [Cu(en)2]2+, log K = 15.4

(d) Cu2+ + 4H2O à [Cu(H2O)4]2+, log K = 8.9 [Level: Easy]

 

Question 11:

Among the following metal carbonyls, the C–O bond order is lowest in

(a) [Mn(CO)6]+

(b) [Fe(CO)5]

(c) [Cr(CO)6]

(d) [V(CO)6] [Level: Difficult]

 

Question 12:

The IUPAC name of [Ni (NH3)4] [NiCl4] is

(a) Tetrachloronickel (II) - tetraamminenickel (II)

(b) Tetraamminenickel (II) - tetrachloronickel (II)

(c) Tetraamminenickel (II) - tetrachloronickelate (II)

(d) Tetrachloronickel (II) - tetrachloronickelate (0) [Level: Moderate]

 

Question 13:

Among the following complexes, optical activity is possible in

(a) [Co(NH3)6]3+

(b) [Co(H2O)2(NH3)2Cl2]+

(c) [Cr(H2O)2Cl2]+

(d) [Co(CN)5NC] [Level: Easy]

 

Question 14:

Ammonia will not form complex with

(a) Ag2+

(b) Pb2+

(c) Cu2+

(d) Cd2+ [Level: Moderate]

 

Question 15:

The ligand N(CH2CH2NH2)3 is

(a) tridentate

(b) pentadentate

(c) tetradentate

(d) bidentate [Level: Moderate]

 

Question 16:

The charge on the central metal ion in the complex [Ni(CO)4] is

(a) + 2

(b) + 4

(c) 0

(d) + 3 [Level: Moderate]

 

Question 17:

As per IUPAC nomenclature, the name of the complex [Co(H2O)4(NH3)2]Cl3 is :

(a) Tetraaquadiaminecobalt (III) chloride

(b) Tetraaquadiamminecobalt (III) chloride

(c) Diaminetetraaquacoblat (II) chloride

(d) Diamminetetraaquacobalt (III) chloride [Level: Moderate]

 

Question 18:

Which among the following will be named as dibromidobis(ethylene diamine) chromium (III) bromide?

(a) [Cr(en)3]Br3

(b) [Cr(en)2Br2]Br

(c) [Cr(en)Br4]

(d) [Cr(en)Br2]Br [Level: Difficult]

 

Question 19:

Which of the following facts about the complex [Cr(NH3)6]Cl3 is wrong?

(a) The complex involves d2sp3 hybridisation and is octahedral in shape.

(b) The complex is paramagnetic.

(c) The complex is an outer orbital complex

(d) The complex gives white precipitate with silver nitrate solution. [Level: Easy]

 

Question 20:

Which of the following has a square planar geometry?

(a) [PtCl4]2–

(b) [CoCl4]2–

(c) [FeCl4]2–

(d) [NiCl4]2–

(At. nos.: Fe = 26, Co = 27, Ni = 28, Pt = 78) [Level: Difficult]

**********

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You must have heard of the phrase “Practice makes a man perfect”. Well, not just a man, practice indeed enhances perfection of every individual.

Practicing questions plays a pivotal role in achieving excellence in exams. Just as the adage goes, "Practice makes perfect," dedicating time to solve a diverse range of exam-related questions yields manifold benefits. Firstly, practicing questions allows students to familiarize themselves with the exam format and types of problems they might encounter. This familiarity instills confidence, reducing anxiety and improving performance on the actual exam day. Secondly, continuous practice sharpens problem-solving skills and enhances critical thinking, enabling students to approach complex problems with clarity and efficiency. Thirdly, it aids in identifying weak areas, allowing students to focus their efforts on improving specific topics. Moreover, practice aids in memory retention, as active engagement with the material reinforces learning. Regular practice also hones time management skills, ensuring that students can allocate appropriate time to each question during the exam. Overall, practicing questions not only boosts exam performance but also instills a deeper understanding of the subject matter, fostering a holistic and effective learning experience.

All About Daily Practice Problems on NEET Chemistry Coordination Compounds NCERT Chapter 9

Our Daily Practice Problems (DPPs) offer a diverse range of question types, including Multiple Choice Questions (MCQs) as well as short and long answer types. These questions are categorized into Easy, Moderate, and Difficult levels, allowing students to gradually progress and challenge themselves accordingly. Additionally, comprehensive solutions are provided for each question, available for download in PDF format - Download pdf solutions as well as Download pdf Questions. This approach fosters a holistic learning experience, catering to different learning styles, promoting self-assessment, and improving problem-solving skills. With our well-structured DPPs, students can excel in exams while gaining a deeper understanding of the subject matter. Hope you found the content on NEET Chemistry Coordination Compounds NCERT Chapter 9 useful.

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