Class 11 Chemistry
Structure of Atom
Question1.
Why all the isotopes of a given element show same chemical behaviour?
Question2.
Wooden ball of 200 g does not move like a wave when it is thrown at a speed of 200 km/h. Calculate the wavelength of the wooden ball and explain why it does not show wave nature.
Question3.
Which of the following statement is incorrect according to Rutherford’s Nuclear model of atom?
(i) The positive charge and most of the mass of the atom was densely
concentrated in extremely small region. This very small portion of the atom
was called nucleus by Rutherford.
(ii) Electrons move in a circular path of fixed energy called orbits.
(iii) Electrons and the nucleus are held together by electrostatic forces of
attraction.
Question4.
The number of radial nodes for 4p orbital is __________.
(i) 3
(ii) 4
(iii) 2
(iv) 1
Question5.
Which of the following sets of quantum numbers are correct?
n l ml
(i) 1 1 +2
(ii) 3 2 +2
(iii) 4 3 –3
(iv) 3 4 –2
Question6.
1) s
2) d
3) p
4) none of the above orbitals
Question7.
Match the following
Subshell No. of Orbitals
s 7
d 3
g 1
p 11
f 5
h 9
Question8.
Question9.
Match the following species with their corresponding electronic configuration.
Atom / Ion Electronic configuration
(i) Cd (a) [Ar] 3d10
(ii) Cu+ (b) [Ar] 4s2 4p3
(iii) As (c) [Kr] 5s1
(iv) Rb (d) [Kr] 4d10 5s2
(e) [Ar] 3d9 4s1
Question10.
Which of the following orbitals are degenerate?
5dxz, 4dxy, 4dyz, 5dyz, 5dxy
Question11.
In which of the following pairs, the ions are iso-electronic?
1) Al3+, N3-
2) Mg3+, O2-
3) F-, Mg+
4) O2-, Na+
Question12.
Show the distribution of electrons in Nitrogen atom using orbital diagram.
Question13.
The Balmer series in the hydrogen spectrum corresponds to the transition from n1 = 2 to n2 = 3,4,5, .......... This series lies in the visible region. Calculate the wave number of line associated with the transition in Balmer series when the electron moves to n = 5 orbit. (RH = 109677 cm–1)
Question14.
When a photon of frequency 1.0 × 1015 s–1 was allowed to hit a metal surface, an electron having 1.988 × 10–19 J of kinetic energy was emitted. Calculate the threshold frequency of this metal. Will electron be emitted if a photon with a wavelength equal to 400 nm hits the metal surface?
Question15.
Give the postulates on which Bohr’s model for Hydrogen atom is based.
Question16.
Thomson explained which of the following properties of atom correctly?
(i) Position of protons, electrons and neutrons in atom.
(ii) Spectra of H-atom.
(iii) Overall neutrality of atom.
(iv) Stability of atom.
Question17.
1) Magnetic quantum number a) shape of the orbital
2) Pauli Exclusion Principle b) Pairing of electrons in the orbitals
belonging to the same subshell does
not take place until each orbital is
singly occupied.
3) Azimuthal quantum number c) No two electrons in an atom can have
the same set of four quantum
numbers
4) Hund’s Rule d) It is impossible to determine the exact
position and exact momentum of a
electron simultaneously.
5) Heisenberg’s Uncertainty e) orientation of the orbital
Principle
Question18.
Which of the following statement/statements about the proton is/are correct?
(i) It is a positively charged particle.
(ii) The mass of proton is approximately equal to the mass of neutron.
(iii) It is a basic constituent of all atoms.
(iv) Canal rays in case of Hydrogen gas consisted of protons.
Question19.
Charge to mass ratio of electron determined by Thomson is equal to
1) 1.779 x 1011 C kg-1
2) 1.758 × 10-11 C kg–1
3) 1.779 x 10-11 C kg–1
4) 1.758 × 1011 C kg–1
Question20.
What is black body & black body radiation?
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