Class 11 Chemistry
Equilibrium
Question1.
The value of Kc for the reaction, N2 (g) + 3H2 (g) ⇌ 2NH3 (g) is 0.50 at 400 °C. Find the value of Kp at 400 °C when concentrations are expressed in mol L-1 and pressure in atmosphere.
Question2.
The first and second dissociation constants of an acid, H2A, are 1 x 10-5 and 5 x 10-10
respectively. The overall dissociation constant of the acid will be:
1) 0.2 x 105
2) 5 x 10-5
3) 5 x 10-15
4) 5 x 1015
Question3.
Nicotinic acid (Ka = 1.4 x 10-5) is represented by the formula HNiC. Calculate its per cent dissociation in a solution which contains 0.10 mole of nicotinic acid per 2 litre of solution.
Question4.
For the hypothetical reactions, the equilibrium constant (K) values are given:
A ⇌ B; K1 = 2;
B ⇌ C; K2 = 4;
C ⇌ D; K3 = 3
The equilibrium constant (K ) for the reaction A ⇌ D is:
1) 48
2) 6
3) 2.7
4) 24
Question5.
'If, in the reaction N2O4 (g) ⇌ 2NO2 (g), x is that part of N2O4 which dissociates, then the number of molecules at equilibrium will be:
a) 1
b) 3
c) 1 + x
d) (1+x)2
Question6.
The solubility of Sb2S3 in water is 1 x 10-5 mol/L at 298 K. What will be its solubility product?
a) 108 x 10-25
b) 1 x 10-25
c) 144 x 10-25
d) 126 x 10-24
Question7.
What is Buffer solution? Give general characteristics of Buffer solution.
Question8.
What is acid & base according to
1) Arrhenius theory
2) Bronsted-Lowry theory
3) Lewis Concept
Question9.
Suppose it is required to make a buffer solution of pH = 4, using acetic acid and sodium acetate. How much of sodium acetate is to be added to 1 litre of N/10 acetic acid? Dissociation constant of acetic acid = 1.8 x 10-5.
Question10.
What is the pH of the buffer solution containing 0.15 mol of NH4OH and 0.25 mol of NH4Cl? Kb for NH4OH is 1.98 x 10-5:
a) 10
b) 9
c) 9.2
d) 10.2
Question11.
The pKa of a weak acid (HA) is 4.5. The pOH of an aqueous buffered solution of HA, in which 50% of the acid is ionised, is:
a) 7.0
b) 4.5
c) 2.5
d) 9.5
Question12.
A certain weak acid has Ka = 1.0 x 10-4. Calculate the equilibrium constant for its reaction with a strong base.
Question13.
The degree of hydrolysis of which of the following salt is independent of the concentration of salt solution?
a) CH3COONa
b) NH4Cl
c) CH3COONH4
d) NaCl
Question14.
Give Le Chatelier’s principle.
Question15.
Give general characteristics of Equilibria involving physical processes.
Question16.
State Equilibrium Law.
Question17.
Give Applications of Solubility Product and Common ion Effect.
Question18.
Mention conjugate base of each of the following:
H3O+, HF, HClO4, NH4+
Question19.
The pKa of weak acid HA is 4.80 and the pKb of a weak base BOH is 4.78. The pH of an
aqueous solution of corresponding salt BA will be:
a) 9.22
b) 9.58
c) 4.79
d) 7.01
Question20.
Equal volumes of three acid solutions of pH 3, 4 and 5 are mixed in a vessel. What will be
the H+ ion concentration in the mixture?
a) 3.7 x 10-3 M
b) 1.11 x 10-3 M
c) 1.11 x 10-4 M
d) 3.7 x 10-4 M
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