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Question:
a solution containing 8.6g/l of urea is isotonic with 5% solution of unknown solute. The molar mass of the solute will be?
Answer:

Moles of urea = mass/ molar mass of urea = 8.6 g/60 g/mol = 8.6/60 mole

Concentration of urea solution = 8.6/60 mole/L

Moles of unknown solution = mass/ molar mass of unknown solution

5% of unknown solution = 5 g /100 ml = 50 g /1000 ml = 50/L

Moles of unknown solute = 50/m moles

Concentration of unknown solution = 50/m mole/L

Therefore,

8.6/60 mole/L = 50/m mole/L

m = 50 x 60/8.6 = 348.9 g/mole

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