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Question:
Order of reactivity of alkyl halide towards SN1 reactions is tertiary.Why?
Answer:

The SN1 reactions are possible depending on the stability of the carbocation formed as an intermediate. So, in case of tertialry alkyl halides, the carbocation formed is most stable followed by secondary alkyl halides and then primary alkyl halides. Ther fore, the order of reactivity of alkyl halides towards SN1 reaction is tertiary>secondary>primary.

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