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Question:
For a first order reaction, show that time required for 99% completion is twice the time required for the completion of 90% of reaction.
Answer:

Given,

Order of reaction = first 

Let Initial amount = 100 g 

Amount in % after 90 % completion = 100 - 90 = 10% 

Amount in g [R]= 10% of 100g = 10g 

Amount in % after 99 % completion = 100 - 99 = 1% 

Amount in g [R]= 1% of 100g = 1g 

Use the formula of first order reaction

We observe that t2 = 2t1 

Hence, for a first order reaction, time required for 99% completion is twice the time required for the completion of 90% of reaction.

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