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Question:
How do we know the boiling point of any substance which has its temperature range beyond, the calibrated value in the thermometer we are using?
Answer:

Foe experimental purposes, the thermometers that are used are scled very high in the range. Moreover, the temperatures are not calculated with thermometers always, but also with thermosetters. These devices allow measurements in the range of thousands on degree celcius or kelvin.

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