

We know that,
22400 lit of nitrogen = 1 mole of nitrogen = 28 gm of nitrogen
So, 5.6 lit = 28x5.6/22400
= 0.007 gm.
Weight of oxide = 11 gm
So, the oxygen component of the oxide = 11 - 0.007
= 10.993 gm
Similarly, weight of second oxide = 15 gm.
Here, weight of oxygen = 10.993 gm,
so weight of nitrogen = 15 - 10.993
= 4.007 gm
So, the amount of nitrogen reacting with a fixed amount of oxygen (10.993 gm) is -
1. in the first case 0.007 gm
2. in the second case 4.007 gm
So they are in ratio 0.007:4.007
= 1:572
It is in a ratio of whole numbers, thus supports the law of multiple proportion.
However, the question may have some mistakes, because a ration of 1:572 is not expected between nitrogen and oxygen. So kindly check the question.
